Naming Organic Compounds (Cambridge O Level Chemistry)

Topic Questions

1a1 mark

Coal gas is made by heating coal in the absence of air.
The list shows the main gases present in coal gas.

carbon dioxide
carbon monoxide
ethene
hydrogen
methane
nitrogen

Which one of these gases is an alkane?

1b1 mark

Draw the structure of a molecule of ethene. Show all of the atoms and all of the bonds.

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1a2 marks

Petrol is a mixture of hydrocarbons and additives. The combustion of petrol in car engines is a major source of air pollution. This is reduced by catalytic converters.

Petrol is obtained from the gasoline fraction, boiling point range 40 °C to 100 °C, from the distillation of petroleum.

Explain the term fraction.

1b6 marks

In many countries, a lead compound of the type Pb(C2H5)n used to be added to petrol to improve its combustion. After combustion, lead oxide was formed.

 
petrol-pump
 
i)
Octane is a constituent of petrol. Write the equation for the complete combustion of octane.
 
C8H18 + .......... O2 → .......... + ..........
 
[2]
 
ii)
Dibromoethane was added to petrol to remove the lead oxide from inside the engine. Lead bromide was formed which escaped into the environment through the exhaust. Leaded petrol cannot be used with a catalytic converter.
 
Give another reason why leaded petrol is no longer used.
 
[1]
 
iii)
What does each of the following tell you about the structure of dibromoethane?
 
dibromo ......................................................................................................................
 
eth ..............................................................................................................................
 
ane .......................................................................................................................
 
[2]
 

iv)
What additional information is needed to draw the structural formula of dibromoethane?
 
[1]
1c2 marks

An analysis of the compound, Pb(C2H5)n, showed that 0.026 moles of Pb was combined with 0.104 moles of C2H5 groups.

What is the value of n? Show how you arrived at your answer.

1d3 marks

Some of the pollutants emitted by vehicle exhausts are carbon monoxide, oxides of nitrogen and unburnt hydrocarbons. Explain how the emission of these gases is reduced by a catalytic converter.

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2a3 marks

Table 2.1 shows some information about the homologous series of unbranched carboxylic acids.

Table 2.1

name

structure

boiling point / °C

methanoic acid

HCOOH

101

ethanoic acid

CH3COOH

118

propanoic acid

CH3CH2COOH

141

butanoic acid

CH3CH2CH2COOH

164

pentanoic acid

CH3CH2CH2CH2COOH

186

 

One of the characteristics of a homologous series is that it has a general formula.

i)
the general formula for the homologous series of unbranched carboxylic acids.

[1]

ii)
Describe two other characteristics of a homologous series.

[2]

2b1 mark

An aqueous solution of propanoic acid is a weak acid.

Define the term acid.

2c2 marks

Butanoic acid reacts with ethanol to make an ester.

State the name of the ester made and draw the displayed formula of the ester linkage.

2d3 marks

Ethanoic acid is a liquid at room temperature.

Describe the changes in the arrangement and movement of the molecules of ethanoic acid

when it is heated from room temperature to 120°C.

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